International: UNS C52100, CDA 521, CuSn8 (EN Standard)
Chinese: QSn8-0.3 (GB/T 4423-1992)
Alias: 8% Tin-Phosphor Bronze, Instrument Bronze, characterized by high tin content (7.0%-9.0% Sn) and phosphorus strengthening (0.03%-0.35% P).
C52100 excels in the tin-phosphor bronze series:
Strength-Conductivity Balance: Tensile strength reaches 860-1035 MPa (hard temper) with 13-15% IACS conductivity, outperforming low-tin phosphor bronzes.
Wear/Corrosion Resistance: Low friction coefficient (0.15-0.25), corrosion rate <0.015 mm/year in seawater/weak acids, resistant to stress corrosion cracking.
Special Properties: Non-magnetic (μ<1.01), cryogenic toughness (effective at -200°C), spark-free upon impact.
Process Adaptability: Excellent cold workability (≤30% deformation), but limited hot workability.
Table 1: Product Forms & Specifications
Form | Size Range | Temper | Standard |
Sheet/Plate | Thickness: 0.1-150mm; Width: 400-1100mm | O60 (Soft), H08 (Hard) | ASTM B103 |
Strip | Thickness: 0.05-2.0mm; Width: 10-600mm | H04, H06 | GB/T 4423 |
Bar (Round/Hex) | Diameter/Width: Ø5-200mm | Y2 (Half-hard), T6 (Aged) | ASTM B139 |
Wire | Diameter: Ø0.1-12mm | Soft, Half-hard | ASTM B103 |
Tube | OD: Ø3-150mm; Wall: 0.2-15mm | Annealed, Hard | GB/T 4423 |
Note: Custom profiles available with ±0.05mm tolerance.
Table 2: Chemical Composition (wt%, Cu bal.)
Element | Req. | Typical | Impurity Max | Function |
Sn | 7.0-9.0 | 8.0 | - | Solid solution strengthening |
P | 0.03-0.35 | 0.15 | - | Deoxidation, grain refinement |
Fe | ≤0.10 | ≤0.02 | 0.10 | Reduces conductivity if excessive |
Pb | ≤0.05 | ≤0.005 | 0.05 | Prevents hot shortness |
Zn | ≤0.20 | ≤0.10 | 0.20 | Trace residual |
Total Impurities | ≤0.50 | ≤0.30 | 0.50 | - |
*Standards: ASTM B159M-2017, GB/T 5231-2012.*
Table 3: Physical Properties (20°C)
Property | Value Range | Unit | Test Method |
Density | 8.80-8.86 | g/cm³ | ASTM B193 |
Electrical Conductivity | 13-15 | %IACS | Annealed |
Thermal Conductivity | 36-50 | W/(m·K) | Steady-state heat flow |
CTE | 18.20×10⁻⁶ | K⁻¹ | 20-300°C |
Elastic Modulus | 110-115 | GPa | Tensile test |
Max Service Temp | 200°C | - | - |
Note: Non-magnetic properties suit precision instruments and explosion-proof applications.
Table 4: Mechanical Properties (Room Temp, Bar Samples)
Property | Annealed (O60) | Half-hard (H02) | Hard (H08) | Test Standard |
Tensile Strength | 365-470 MPa | 655-795 MPa | 860-1035 MPa | ASTM E8 |
Yield Strength | 150-200 MPa | 450-550 MPa | 750-850 MPa | ASTM E8 |
Elongation (δ₁₀) | ≥40% | ≥15% | ≥5% | GB/T 228.1 |
Hardness (HV) | 70-120 | 160-190 | 200-250 | ASTM E92 |
Fatigue Strength (10⁷ cycles) | 140 MPa | 240 MPa | 300 MPa | Rotating bending |
*Note: Samples Ø5-12mm (longitudinal); cold working significantly improves elastic limit.*
Strength-Wear Balance: Hardness up to HV 250 (hard temper), 50% higher wear resistance vs. brass (PV limit: 2.5 MPa·m/s).
Comprehensive Corrosion Resistance: Seawater corrosion rate <0.015 mm/year, resists microbial adhesion.
Cryogenic Suitability: No brittleness at -200°C for superconducting/aerospace components.
Cost Efficiency: 40% lower cost than beryllium copper, avoids toxicity issues, no solution treatment needed.
Precision Springs: High-load contact springs, relay reeds, bellows (excellent stress relaxation resistance).
Wear Parts: Bearing bushes, gear shafts, marine propeller sleeves (self-lubricating service).
Electrical Contacts: High-reliability connectors, micro-motor brushes (balances conductivity/elasticity).
Safety Equipment: Explosion-proof tools, spark-free drill bits (oil rigs, mining maintenance).
Hot Working: Strictly 650-750°C; >800°C causes grain growth, <650°C increases deformation resistance. Rapid cooling required post-rolling.
Cold Working: ≤30% reduction per pass; intermediate anneal (600-650°C×1h). Acid-clean oxide layers before cold drawing.
Welding: Avoid fusion welding (grain boundary embrittlement). Prefer brazing (BAg-5 filler) or diffusion bonding. Post-weld anneal at 500-550°C.
Surface Treatment: Electroless nickel or chromate passivation for corrosion resistance. Prohibit lead-containing coolants to prevent SCC.
Marine: Seawater pump seals (≥10-year design life), resists seawater corrosion/cavitation.
Aerospace: Aircraft sensor springs (Airbus A350 certified), withstands high vibration.
Electronics: 5G connector contacts (>100k mating cycles), ensures signal stability.
Energy: Nuclear valve guides (resists radiation oxidation/fretting wear).
A1: Bronze C52100 has higher Sn (8% vs. 6.5%), 20% higher strength/wear resistance, but 15% higher cost. Use C51900 for general springs; C52100 for high-stress wear parts (bearings, gears).
A2: Caused by excessive deformation/surface defects:
Limit per-pass reduction to ≤25%;
Acid-clean pre-processing;
Intermediate anneal (620°C×1h).
A3: Fusion welding risks embrittlement. Recommended:
Brazing: BAg-5 filler (650-750°C), joint strength ≥300 MPa;
Diffusion Bonding: 850°C×2h + 50 MPa pressure (precision components).
A4: Maximum continuous service: 200°C; short-term exposure: 400°C. For >250°C, apply nickel plating.
Standard | Code | Scope |
USA | ASTM B103/B103M-2019 | Plate, Sheet, Strip, Rolled Bar |
ASTM B139/B139M-2013 | Rod and Bar | |
China | GB/T 4423-1992 | Wrought Copper Alloy Bars |
GB/T 5231-2012 | Chemical Composition & Product Forms | |
International | ISO 427:2016 | Wrought Copper Alloys (CuSn8 equivalent) |
EN 12163:2016 | Rod for General Purposes (CuSn8) | |
Japan | JIS C5210 | Phosphor Bronze Strip for Electronics |
Chemistry: ASTM E54 (Sn), ASTM E62 (P)
Mechanical: ASTM E8 (tensile), ASTM E92 (Vickers hardness)
Metallography: ASTM E112 (grain size)
Note: Data synthesized from ASTM, GB, JIS, and manufacturer specifications. Performance may vary slightly with processing. Conduct application-specific validation for critical uses.
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