International: UNS C51900, CDA 519, CuSn6 (EN Standard)
Chinese: QSn6.5-0.1 (GB/T 4423-1992)
Alias: Tin-phosphor bronze, Instrument bronze, featuring 6-7% tin and 0.1-0.25% phosphorus.
C51900 balances high strength with functionality:
High Strength & Elasticity: Tensile strength ≥480 MPa (cold-worked), elastic modulus 115 GPa; ideal for precision springs.
Corrosion/Wear Resistance: Corrosion rate <0.01 mm/year in atmosphere/freshwater; low friction coefficient (0.18-0.25).
Special Properties: Non-magnetic (μ<1.01), spark-resistant for explosion-proof applications.
Processing Flexibility: Excellent hot/cold workability, weldability, brazing, and machinability.
Table 1: Product Forms & Specifications
Form | Size Range | Temper | Standard |
Sheet/Plate | Thickness: 0.1-50mm; Width: 100-1500mm | O60 (Soft), H08 (Hard) | ASTM B103 |
Strip | Thickness: 0.05-2.0mm; Width: 10-600mm | H04, H06 | GB/T 4423 |
Bar (Round/Hex) | Diameter/Width: Ø5-200mm | Y2 (Half-hard), T6 (Aged) | ASTM B139 |
Wire | Diameter: Ø0.1-12mm | Soft, Half-hard | ASTM B103 |
Tube | OD: Ø3-150mm; Wall: 0.2-10mm | Annealed, Hard | GB/T 4423 |
Note: Custom sizes (e.g., hex bars, profiles) available with ±0.05mm tolerance.
Table 2: Chemical Composition (wt%, Cu bal.)
Element | Req. | Typical | Impurity Max | Function |
Sn | 6.0-7.0 | 6.5 | - | Strength, hardness & corrosion resistance |
P | 0.10-0.25 | 0.15 | - | Deoxidation, fluidity & wear resistance |
Fe | ≤0.05 | ≤0.02 | 0.05 | Excessive amounts reduce conductivity |
Pb | ≤0.02 | ≤0.005 | 0.02 | Controls hot shortness |
Zn | ≤0.30 | ≤0.10 | 0.30 | Trace residual |
Total Impurities | ≤0.10 | ≤0.05 | 0.10 | - |
*Standards: GB/T 4423-1992, ASTM B139.*
Table 3: Physical Properties (20°C)
Property | Value Range | Unit | Test Condition |
Density | 8.80-8.86 | g/cm³ | ASTM B193 |
Electrical Conductivity | 15-16 | %IACS | Annealed |
Thermal Conductivity | 38-42 | W/(m·K) | Steady-state heat flow |
CTE | 18.5×10⁻⁶ | K⁻¹ | 20-300°C |
Elastic Modulus | 110-115 | GPa | Tensile test |
Melting Point | 1000-1020 | °C | - |
Table 4: Mechanical Properties (Room Temp, Bar Samples)
Property | Annealed (O60) | 1/4 Hard (H02) | Hard (H08) | Test Standard |
Tensile Strength (σb) | ≥325 MPa | ≥480 MPa | ≥620 MPa | ASTM E8 |
Yield Strength (σ₀.₂) | ≥150 MPa | ≥400 MPa | ≥550 MPa | ASTM E8 |
Elongation (δ₅) | ≥30% | ≥13% | ≥5% | GB/T 228.1 |
Hardness (HV) | 85-100 | 150-180 | 200-230 | ASTM E92 |
Fatigue Strength (10⁷ cycles) | 140 MPa | 240 MPa | 300 MPa | Rotating bending |
*Note: Sample diameter 5-12mm (longitudinal direction).
Strength-Conductivity Balance: 15-16% IACS + 480 MPa tensile strength (H02), outperforms C51000/C51100.
Extended Wear Life: 2× longer bearing life vs. brass (PV limit: 2.5 MPa·m/s).
Cryogenic Suitability: No brittleness at -200°C for aerospace/superconducting equipment.
Processing Compatibility: Supports cold heading, stamping (≤30% deformation), TIG welding (SCu5210 filler).
Electronics: High-reliability connectors, relay springs, test probes (>100k mating cycles).
Precision Instruments: Hairsprings, diaphragms, brush holders, gears (non-magnetic).
Industrial: Bellows, bearing bushes, chemical pump seals (resists weak acids/seawater).
Transportation: Aircraft sensor springs, automotive seat brackets (cold-stamped).
Hot Working: Strictly 750-770°C; >800°C causes grain growth, <700°C increases deformation resistance.
Cold Working: ≤30% per-pass reduction; intermediate anneal (600-650°C×1h) to relieve hardening.
Welding: Prefer TIG (SCu5210 filler + 200-250°C preheat); post-weld anneal at 500-550°C.
Surface Treatment: Avoid lead-containing coolants to prevent SCC; chromate passivation enhances corrosion resistance.
Aerospace Connectors: Stable performance under high vibration (Airbus A350 certified).
Marine Valve Bushings: ≥10-year design life in seawater.
Smart Meter Springs: Elastic hysteresis <0.05% (meets Class 0.1 accuracy).
Explosion-Proof Tools: Spark-free impact for oil platform maintenance.
A1: C51900 has higher Sn (6.5% vs. 4%), 30% higher strength/elasticity, but 20% higher cost. Use C51100 for general springs; C51900 for high-stress springs/wear parts.
A2: Corrosion rate <0.015 mm/year (static). For flow >2 m/s, use passivation/cathodic protection; avoid direct contact with stainless steel.
A3: Caused by excessive deformation/surface defects. Solutions:
1. Limit per-pass reduction to ≤25%;
2. Acid-clean oxide layers pre-processing;
3. Intermediate anneal (620°C×1h).
A4: Verify parameters:
Annealed: 600-650°C + air cooling;
Aging: 320-340°C×2-3h (hardness ↑10-15%).
Standard | Code | Title |
China | GB/T 4423-1992 | Wrought Copper Alloy Bars |
GB/T 5231-2012 | Chemical Composition & Forms of Wrought Copper Alloys | |
USA | ASTM B103/B103M-2019 | Phosphor Bronze Plate, Sheet, Strip, and Rolled Bar |
ASTM B139/B139M-2013 | Phosphor Bronze Rod and Bar | |
International | ISO 427:2016 | Wrought Copper Alloys - Composition & Product Forms |
EN 12163:2016 | Copper and Copper Alloys - Rod for General Purposes (CuSn6 equivalent) | |
Japan | JIS C5191 | Phosphor Bronze Strip for Electronic Equipment |
Chemistry: ASTM E54 (Sn), ASTM E62 (P)
Mechanical: ASTM E8 (tensile), ASTM E92 (hardness)
Metallography: ASTM E112 (grain size)
Note: Data synthesized from ASTM, GB, JIS, and manufacturer specs. Performance may vary slightly with processing. Conduct application-specific validation before use.
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